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991.
Simple and sensitive electrochemical method for the determination of metronidazole, based on a nanostructured film coated glassy carbon electrode (GCE), is described. Multi-walled carbon nanotubes (MWNT) was dispersed into water in the presence of a hydrophobic surfactant to give very stable and homogeneous MWNT suspension, and a MWNT-film coated GCE was achieved via evaporating solvent. Metronidazole yields a well-defined reduction peak whose potential is −0.71 V at the MWNT-film coated GCE in pH 9.0 Britton-Robinson buffer. Compared with bare GCE, the MWNT-film modified GCE significantly enhances the reduction peak current of metronidazole. All the experimental parameters were optimized for the determination of metronidazole. The detection limit is 6×10−9 mol/l at 2 min accumulation. This method has been successfully used to determine metronidazole in the drugs. Furthermore, results obtained by the proposed method have been compared with spectrophotometric method. 相似文献
992.
993.
壳聚糖季铵盐的合成及结构表征 总被引:39,自引:4,他引:39
用异相法合成了水溶性壳聚糖季铵盐衍生物,并用红外光谱及核磁共振谱进行结构表征。结果表明:在中性反应条件下,壳聚糖分子的季铵盐衍生化反应主要发生于亲该中心C2位的氨基上,所合成的壳聚糖季铵盐衍生物可直接溶解于水。其水溶液可以任意比例与乙醇、丙二醇、甘油等混溶。 相似文献
994.
995.
Gerhard Laus Johannes Schütz Herwig Schottenberger Max Andre Klaus Wurst Mariana Spetea Karl‐Hans Ongania AdrianG. Müller Helmut Schmidhammer 《Helvetica chimica acta》2003,86(10):3274-3280
The two diastereoisomeric ferrocenyl‐substituted orvinols 2 and 3 were prepared. The modified alkaloids are still able to interact with opioid receptors (see Table). The ferrocene moiety allows highly selective and sensitive electrochemical detection. The X‐ray crystal structure of the major isomer 2 was determined. The combination of a metallocene and a morphinan alkaloid holds promise for useful antitumor activity. 相似文献
996.
997.
998.
TheA
1
–X
1
+ system of SnO is studied by laser- induced fluorescence excitation spectroscopy using isotopically enriched tin Sn116. The rotational structure analysis has been carried out for 6-0, 5-0, 2-0 bands. All these spectra were well resolved only with few perturbed lines in 2-0 band. Rotational constantsB
2,B
5,B
6 and henceB
e
,
e
e
have been obtained for the Sn116O molecule. An extension of perturbation study on 4-0 band has been made showing the maximum perturbation occurs at different J values for different isotopes. 相似文献
999.
S. Barlag H. Becker T. Böhringer M. Bosman V. Castillo V. Chabaud D. Buchholz C. Damerell C. Daum H. Dietl H. Fawcett S. Gill A. Gillman R. Gilmore T. Gooch L. Görlich P. Gras Z. Hajduk E. Higon B. D. Hyams D. P. Kelsey J. Kemmer R. Klanner U. Kötz S. Kwan B. Lücking G. Lütiens G. Lutz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé J. Richardson G. De Rijk K. Rybicki H. J. Seebrunner U. Stierlin H. G. Tiecke M. Turala G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers A. Wylie T. Zeludziewicz ACCMOR Collaboration 《Zeitschrift fur Physik C Particles and Fields》1987,37(1):17-23
We have measured the lifetimes of hadronically produced charged and neutralD mesons using silicon microstrip detectors and an active silicon target in the NA32 spectrometer at the CERN SPS. We obtainτ D± = (10.9± 1.5 1.9 )·10?13s andτ D (?)10 = (4.2±0.5)·10?13s based on 59 and 90 fully reconstructed decays respectively, giving a ratioτ D±/τ D (?)10 of 2.6 ±0.5. 相似文献
1000.
G. H. Wang X. Y. Li Y. Y. Lu Y. Z. Zhu H. W. Wang L. Dou R. X. Yu 《Zeitschrift für Physik B Condensed Matter》1987,65(3):347-351
12 MeV electron beams with different doses of 4, 8, 16 and 32 Mrad from LINAC designed by Nanjing University have been used to irradiate polypropylene films and their structures studied by X-ray diffraction afterwards. We have found that the electron irradiation does not change the total crystallinity of polypropylene but greatly inflences its crystal structure with increase of phase and decrease of phase as irradiation dose increases (within 16 Mrad). However, it is unexpected that the structure of irradiated sample with 32 Mrad are similar to that of the control sample. This behavior has also been observed in positron annihilation lifetime measurements. 相似文献